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Comparison between micro- and nanosized copper oxide …
Uptake studies revealed an intracellular copper overload in the soluble fractions of both cytoplasm and nucleus, reaching up to millimolar concentrations in case of CuO NP and considerably lower levels in case of CuO MP and CuCl 2. Moreover, CuCl 2 caused copper accumulation in the nucleus only at cytotoxic concentrations. Gene …
Pesticidal Copper (I) Oxide: Environmental Fate and Aquatic …
Copper (I) oxide is an IUPAC name; however, in this chapter synonymous names like copper oxide and cuprous oxide will be used interchangeably. 1.2 Physical and Chemical Properties Copper oxide dissolves in strong acids, ammonium hydroxide, and aqueous ammonia and its salts (Goh 1987 ).
Gold processing
Gold processing - Mining, Concentrating, Refining: The nature of the ore deposit determines the mining and mineral processing techniques applied. Oxide ore deposits are frequently of such low grade (e.g., 3 to 10 parts per million) that extensive mineral processing cannot economically be justified. In this case they are merely shattered by explosives and then …
Minimizing nitrous oxide in biological nutrient removal from …
In this study, nitrous oxide (N 2 O) production during biological nutrient removal (BNR) from municipal wastewater was reported to be remarkably reduced by controlling copper ion (Cu 2+) concentration.Firstly, it was observed that the addition of Cu 2+ (10–100 μg/L) reduced N 2 O generation by 54.5–73.2 % and improved total …
Correlation between molar concentration and properties of …
X-ray diffraction patterns of concentration-varied sprayed CuO thin films are shown in Fig. 3.1 and it can be observed that structural properties of the spray-synthesized copper oxide thin films have been widely influenced by molar concentration. 0.10 M specimen exhibited diffraction peaks identical to tenorite phase (CuO) of copper oxide ...
Current Status of Copper-Ore Processing: A Review
ores containing a low concentration of copper in the ore (oxide, mixed ores, and secondary sulfide ores) can be affected by the leaching of ground ore followed by …
Facile route for preparation of cuprous oxide/copper/cupric oxide …
Cuprous oxide/copper/cupric oxide (Cu 2 O/Cu/CuO) nanoparticles were successfully prepared by a combination of anodic dissolution and controlled redox reaction between NaOH and glucose in the solution. The as-prepared materials exhibited distinct morphologies by altering glucose concentrations with a fixed NaOH amount (i.e., 0.15 M).
Electrodeposition of Cu2O: growth, properties, and …
In 1926, copper oxide was employed as one of the first semiconductors as a diode, which consisted of oxidized copper disks . Subsequently, ... (II) sulfate, 4 M sodium lactate, and variable concentration of copper(II) chloride . The pH of the solution was 7.5, adjusted by a solution of NaOH. The Cl doping level could be controlled by the ...
Current Status of Copper-Ore Processing: A Review
ores containing a low concentration of copper in the ore (oxide, mixed ores, and secondary sulfide ores) can be affected by the leaching of ground ore followed by solvent extraction and electrowinning. This tech-nology is applied in a number of large copper produc-tions, including Escondida (Chile), Collahuasi
Exploring the cytotoxicity mechanisms of copper ions and copper oxide …
Copper oxide nanoparticles (CuO NPs) are widely applied in various products, including food, cosmetic, biomedical, and environmental goods. Despite their broad use, potential risks are still associated with these NPs, therefore, the aim of this study is to delve deeper into the cytotoxic effects of 85 nm CuO NPs on kidney MDCK and …
Experimental and Kinetic Modeling Investigation of Copper …
Abstract In the present work, the leaching behavior of copper from an oxide/sulfide ore was assessed in two work phases including process optimization and kinetics modeling. In the first phase, the individual and synergistic impacts of the influential parameters such as sulfuric acid concentration, liquid/solid ratio, pulp mixing rate, …
Copper Mining and Processing: Processing Copper Ores
Oxide ores are generally processed using hydrometallurgy. This process uses aqueous (water-based) solutions to extract and purify copper from copper oxide ores at ordinary temperatures, usually in three steps: heap leaching, solvent extraction, and electrowinning. Heap Leachingis the process of using percolating …
Effect of Copper Oxide Concentration on the Formation …
Effect of Copper Oxide Concentration on the Formation and Persistency of Environmentally Persistent Free Radicals (EPFRs) in Particulates. Lucy W. Kiruri, …
Flotation of copper oxide minerals: A review
Copper oxide minerals are important copper resources, which include malachite, azurite, chrysocolla, cuprite, etc. Flotation is the most widely used method for the enrichment of copper oxide minerals in the mineral processing industry. ... The concentration of free copper ions on the cuprite surface is insufficient, and poor …
Reaction of Copper and concentrated sulphuric acid
The copper takes the [O] and become CuO while sulfuric acid become sulfur dioxide. Then CuO reacts with remaining sulfuric acid to form CuX2SOX4 C u X 2 S O X 4. This is a grossly simplified version of what probably happens, but it gives you a sense of why conc. HX2SOX4 H X 2 S O X 4 can react with Cu. – S R Maiti. Apr 14, 2021 at 9:59.
Toxicity of copper oxide nanoparticles: a review study
Throughout this review, emphasis has been done on the information relating to synthesis methodologies of copper oxide nanoparticles (CuO NPs), characterisation, advantages and disadvantages, experimental designs related to concentration of NPs, models used, duration of the CuO NPs exposure and assessment of endpoints.
Effect of Copper Oxide Concentration on the Formation …
O to obtain particles with different copper oxide concentrations: 0.25, 0.5, 0.75, 1, 2, 3, and 5 wt %. Samples were left to adsorb copper nitrate for 24 h at room temperature and then dried in the air at 120 °C for 12 h before calcination in the air at 450 °C for 5 h to form Cu(II)O. EPFR Formation. The adsorbate chemicals, phenol (PH,
Stability and lifetime of diffusion-trapped oxygen in oxide …
The oxygen concentration in the most stable oxide-derived Cu increases with an increase of the pH, potential or specific surface area. In long electrochemical experiments, the catalyst would be...
Particle size and concentration dependent toxicity of copper oxide …
The results show that the effects of copper compound type (Cu type; p < 0.01), copper concentration (C; p < 0.01), and the interaction between Cu type × C (p < 0.05) were statistically significant for seed production in soybean (Table 1).Our results show particle size- and concentration-dependent inhibition in seed yield in soybean upon …
Comparison between micro- and nanosized copper oxide …
Cellular uptake and intracellular distribution of copper. Cellular uptake and intracellular distribution of copper was analysed after 24 h incubation with different concentrations of CuO NP, CuO MP and CuCl 2 via graphite furnace atomic absorption spectrometry (GF-AAS). When working with particles, one problem consists in the fact …
Folic Acid Determination in Food Samples Using Green Synthesized Copper
Copper (II) oxide nanoparticles (CuONPs) were green synthesized using Ocimum basilicum leaves aqueous extract in which polyphenols act as reducing and stabilizing agents. The synthesized CuONPs were characterized using X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, transmission electron …
Tinospora cordifoliaapproached copper oxide nanoparticles …
In the present work, we successfully synthesized copper oxide nanoparticles (CuO-NPs) via the green route using different concentrations of Tinospora cordifolia (TC) leaf extract.While adding TC leaf extract to copper acetate solution, the solution turned from bluish to dark green due to the formation of nanostructured copper oxide particles, …
Fluorite as indicator mineral in iron oxide-copper-gold …
Iron oxide-copper-gold (IOCG) deposits are a globally important but diverse group of hydrothermal ore deposits showing similarities to porphyry Cu-Au, sedimentary Cu and skarn deposits, reflecting variable fluid chemistry, links to intrusions and tectonic settings. ... The measured concentrations across the entire mass range were within the ...
Dissolution kinetics and solubility of copper oxide
Nano copper oxide (CuO NP) was added to eight soils to study the effect of aging time of copper on the concentration of diethylenetriaminepentaacetic acid (DTPA)-extracted copper (DTPA-Cu), with bulk copper oxide (CuO BP) and copper nitrate [Cu(NO3)2] used for comparison. Moreover, the effect of soil properties on the …
Ultrasensitive electrochemical detection of glyphosate using …
Briefly, a mixture of graphene oxide (synthesized using a modified Hummer's method [33] and copper nitrate trihydrate (Cu(NO 3) 2 ·3 H 2 O Sigma-Aldrich), both in a concentration of 1 mg mL-1, was nebulized throughout a tubular furnace at 400 °C under nitrogen gas flow of 1 L min-1, at room pressure.
An investigation into the leaching behaviour of copper oxide …
The two parameters (glycine concentration and initial solution pH) studied in this work have been found to influence the leaching of the copper oxide minerals. Greater copper extraction and faster leach rates can be achieved by using a high Gly:Cu ratio (8:1), but a Gly:Cu ratio of 4:1 (i.e. double stoichiometric requirement) gives acceptable ...
Antibacterial and Biocompatible Titanium-Copper Oxide …
Discs coated with TiCuO 80% copper showed mean copper ion concentration at 24 hours of 269.4 µmol/L (SD = 25.2 µmol/L) and this concentration was lower than previously published TC50 for similar human cell lines at 24 hours (344 µmol/L, SEM = 44 µmol/L).
Leaching of copper oxide with different acid solutions
The effect of temperature on the rate of copper dissolution from CuO when leached in the three inorganic acids was investigated over a temperature range of 30–50 °C at acid concentration of 0.5 M, stirring speed of 400 rpm and l/s = 10 ml/g. Fig. 5 shows that temperature has a significant effect on the acceleration of copper dissolution with …
Electrical and optical properties of copper oxide thin films …
Copper oxides (CuO, Cu 2 O) have promising application potential in sensors or solar cells. In this study, copper oxide thin films were prepared by reactive DC magnetron sputtering using helicon plasma. A pure copper target was sputtered with Ar gas in an O 2 atmosphere with a DC sputtering power in the range of 10–40 W, while the …
Environmental behavior, potential …
Copper oxide nanoparticles (CuO NPs) are widely used in many industries. The increasing release of CuO NPs from both intentional and unintentional sources into the environment may pose risks to rice …
Sixteen years of canine hepatic copper concentrations …
The revised copper recommendation by the AAFCO was prompted from research that showed decreased serum copper and hemoglobin concentrations in dogs fed a diet that utilized copper oxide instead of copper sulfate, likely due to the low bioavailability of copper oxide (approx 5%) compared to copper sulfate (approx 60% to …
Green synthesis, characterization, antibacterial, and …
The antibacterial activity mechanism of copper oxide nanoparticles is dependent on the size, structure, and concentration of copper oxide. The three major ways that antibacterial activity follows ...
Particle size and concentration dependent toxicity of copper oxide …
Herein, we investigated potential phytotoxicity of copper oxide nanoparticles (CuONPs) on seed yield, focusing on particle size- and concentration-dependent responses of multiple antioxidant defense biomarkers, in soil-grown Glycine max (cv. Kowsar) during its lifecycle. To this end, we synthesized three distinct sizes CuONPs …
Ore-Grade Estimation from Hyperspectral Data Using
Here, we propose the use of convolutional neural networks on hyperspectral data to estimate Cu concentration in drill cores at the Olympic Dam iron oxide copper-gold deposit. The Cu concentration data obtained by drill core geochemical analysis and the mean spectra between the analyzed intervals obtained from hyperspectral data were …
Characterization of electrochemical deposition of copper …
The point and in-depth analysis identified copper(I) oxide in the form of different size crystals depending on the concentration of the copper(II) sulphate solution.
Aquatic Life Criteria
Copper is an essential nutrient at low concentrations, but is toxic to aquatic organisms at higher concentrations. In addition to acute effects such as mortality, chronic exposure to copper can lead to adverse effects on survival, growth, reproduction as well as alterations of brain function, enzyme activity, blood chemistry, and metabolism.
Chemistry of Copper
If you trace the reacting proportions through the two equations, you will find that for every 2 moles of copper(II) ions you had to start with, you need 2 moles of …
Stability and lifetime of diffusion-trapped oxygen in oxide …
The oxygen concentration in the most stable oxide-derived Cu increases with an increase of the pH, potential or specific surface area. ... Oxide-derived copper is well-known as a CO2 reduction ...
Effect of copper oxide concentration on the formation and …
The highest EPFR yield was observed for CuO concentrations between 1 and 3% in relation to MCP and phenol adsorption. However, radical density, which is expressed as the number of radicals per copper atom, was highest at 0.75-1% CuO loading. For 1,2-dichlorobenzene adsorption, radical concentration increased linearly …